Rhodium(I)-catalysed asymmetric hydrosilylation of ketones using new diferrocenyl dichalcogenides (R,S)-{[EC5H3CHMe(NMe2)]Fe(C5H5)}2(E = S, Se, Te), as chiral ligands
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 1375-1376
- https://doi.org/10.1039/c39940001375
Abstract
The new chiral compounds, (R,S)-di[2-(1-dimethylaminoethyl)ferrocenyl] dichalcogenides (R,S)-{[EC5H3CHMe(NMe2)]Fe(C5H5)}2(E = S, Se, Te), work effectively as chiral ligands for the rhodium(I)-catalysed asymmetric hydrosilylation of alkyl aryl ketones resulting in high enantiomeric excess and moderate chemical yields.Keywords
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