Measurement of the coupling constants¹J(⁵⁷Fe–¹³C) and¹J(⁵⁷Fe–³¹P) in phosphine and carbonyl complexes of iron

1 January 1971

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications

No. 19,p. 1173-1174
https://doi.org/10.1039/c29710001173

Abstract

¹ J(⁵⁷Fe–¹³C) for [Fe(CO)₅] and ¹J(⁵⁷Fe–³¹P) for [Fe(CO)₄(PEt_nPh_3–n)](n= 1–3) are reported; it is concluded that these complexes probably undergo intramolecular carbonyl exchange at room temperature.

Keywords

IRON
COUPLING CONSTANT

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Measurement of the coupling constants1J(57Fe–13C) and1J(57Fe–31P) in phosphine and carbonyl complexes of iron

Abstract

Keywords

Measurement of the coupling constants¹J(⁵⁷Fe–¹³C) and¹J(⁵⁷Fe–³¹P) in phosphine and carbonyl complexes of iron