High Oxidation State Organometallic Chemistry, A Challenge—the Example of Rhenium

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Abstract
Homogeneous catalysis as the major industrial outlet of organometallic basic research has been enjoying great benefit from organotransition metal species that promote bond forming between hydrocarbon fragments. Most of the commercially important processes that serve to produce large‐volume organic feedstock chemicals such as linear α‐olefins (Shell Higher Olefins Process), linear aldehydes (hydroformylation), acetaldehyde (Wacker‐Hoechst), acetic acid (Monsanto), adiponitrile (DuPont hydrocyanation of butadiene) operate at low‐valent metal centers. It is thus hardly surprising that by far the most part of organometallic research during the past few decades has been directed towards an understanding and the improvement of these catalytic reactions as well as towards the related stoichiometric chemistry. As a matter of consequence, our present knowledge on high‐valent organotransition metal compound is comparatively shallow, nor do we know much about the chemical relationship and interconvertability of high and low oxidation states within a given class of compounds. In this article I want to point out some ostensibly challenging perspectives of future organometallic research by describing a novel class of high oxidation state organorhenium compounds as well as by speculating on possible generalizations for other transition metals.

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