Regioselective Tetrametalation of Ferrocene in a Single Reaction: Extension of s-Block Inverse Crown Chemistry to the d-Block
- 10 October 2001
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 40 (20) , 3902-3905
- https://doi.org/10.1002/1521-3773(20011015)40:20<3902::aid-anie3902>3.0.co;2-t
Abstract
Remarkably, four hydrogen atoms have been regioselectively removed from the 1,1′,3,3′‐positions of ferrocene in a single reaction leading to the formation of the new macrocyclic host–guest complex [{Fe(C5H3)2}Na4Mg4{iPr2N}8] (see picture). This novel addition to the s‐block metal inverse crown family possesses a tetrasodium–tetramagnesium amido (Na4Mg4N8)4+ ring to complete a series of 8, 12, 16, and 24‐membered rings.This publication has 12 references indexed in Scilit:
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