The relationship between the energies of carbanions, R–, and their lithiated counterparts, RLi. An ab initio study
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 882-884
- https://doi.org/10.1039/c39810000882
Abstract
While the methyl stabilisation energies of fifteen C1–C3 organolithium compounds, RLi, reflect (attentuation factor = 0·71) the methyl stabilisation energies of the corresponding anions, R–, deviations are found when the degree of charge localisation or delocalisation is changed significantly by association with lithium.Keywords
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