Bis-boranes in the frustrated Lewis pair activation of carbon dioxide
- 4 January 2011
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 47 (6) , 1833-1835
- https://doi.org/10.1039/c0cc04791k
Abstract
Using a frustrated Lewis pair approach, the 1,1-bis-(C6F5)2BOB(C6F5)2 is shown to bind CO2 in a monodentate fashion, while the bis-boranes (X2B)2CCMe2 (X = Cl, C6F5) give bidentate chelation of CO2 affording unique heterocycles.Keywords
This publication has 28 references indexed in Scilit:
- Carbon Dioxide Capture: Prospects for New MaterialsAngewandte Chemie International Edition in English, 2010
- Cyclizations via Frustrated Lewis Pairs: Lewis Acid Induced Intramolecular Additions of Amines to Olefins and AlkynesChemistry – A European Journal, 2010
- A Systematic Investigation of Factors Influencing the Decarboxylation of Imidazolium CarboxylatesThe Journal of Organic Chemistry, 2009
- Metal-free hydrogen activation and hydrogenation of imines by 1,8-bis(dipentafluorophenylboryl)naphthaleneChemical Communications, 2009
- Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine PairsJournal of the American Chemical Society, 2009
- Lutidine/B(C6F5)3: At the Boundary of Classical and Frustrated Lewis Pair ReactivityJournal of the American Chemical Society, 2009
- Transformation of Carbon DioxideChemical Reviews, 2007
- Making Plastics from Carbon Dioxide: Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO2Chemical Reviews, 2007
- Facile Heterolytic Cleavage of Dihydrogen by Phosphines and BoranesJournal of the American Chemical Society, 2007
- Tris(pyrazolyl)borate complexes of yttrium. X-ray crystal structures of [HB(pz)3]2YCl(Hpz) and {[HB(pz)3]Y(.mu.-O2CCH3)2}2 (pz = pyrazolyl ring)Inorganic Chemistry, 1988