A novel unimolecular heterolytic scission of the sulphur–sulphur bond in a symmetrical disulphide
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 15,p. 928-929
- https://doi.org/10.1039/c29700000928
Abstract
The thermal heterolytic scission of two symmetrical disulphides to give the parent thiol and a mesoionic compound containing two fewer hydrogen atoms is shown to follow first-order kinetics in a variety of solvents; there is a linear correlation between log k and the polarity parameters Y and Z.Keywords
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