Synthesis and characterization of chromium(II) complexes of tris(2-diphenylphosphinoethyl)phosphine and o-phenylenebis(dimethylarsine)

Abstract
The preparation and properties of new high-spin five-co-ordinate and low-spin six-co-ordinate chromium(II) complexes are reported, [Cr(tdpep)X][BPh4][X = Cl, Br, or I; tdpep = tris(2-diphenylphosphinoethyl)phosphine] and [Cr(pdma)2X2][X = Cl, Br, or I; pdma =o-phenylenebis(dimethylarsine)] respectively.
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