Transition-metal complexes of methylenecyclopropanes: ring-opening reactions promoted by palladium(II)
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 686-688
- https://doi.org/10.1039/c39740000686
Abstract
A variety of stable 1,2-η-bonded methylene cyclopropane complexes of RhI, IrI, Pto, and PtII are reported; isomers of Feist's acid dimethyl ester react with PdCl2(MeCN)2 to yield 1,3-enyl complexes of palladium-(II); stable alkyl complexes of PdII; containing β-hydrogen atoms are reported, and their stability is discussed.Keywords
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