ISOTOPIC EXCHANGE REACTIONS IN THE SYSTEM BROMINE – BROMATE – HYPOBROMOUS ACID
- 1 August 1951
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 29 (8) , 655-665
- https://doi.org/10.1139/v51-074
Abstract
Radiotracer studies with Br82 show that bromine and bromate ion in perchloric acid solution undergo isotopic exchange at a measurable rate. The kinetics of the process suggest that secondary chemical reactions occur, leading to the formation of significant concentrations of hypobromous acid in the system. The isotopic exchange between hypobromous acid and bromine is complete within the time required to separate these species.Keywords
This publication has 3 references indexed in Scilit:
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- Halogen-Halide Exchange Reactions in Aqueous SolutionJournal of the American Chemical Society, 1939