Synthesis of (3S,4R)-eldanolide and (5S,12R)-leukotriene-B4 through photolysis of optically active hydroxy-7,7-dimethylbicyclo[3.2.0]heptanones
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1166-1168
- https://doi.org/10.1039/c39850001166
Abstract
Photoisomerisation of 3-hydroxy-7,7-dimethylbicyclo[3.2.0]heptan-6-ones is the key step in a new route to the pheromone eldanolide while leukotriene-B4 is available through a photolytic retro[2 + 2] reaction of 2-hydroxy-7,7-dimethylbicyclo[3.2.0]heptan-6-ones.Keywords
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