Thermotropic Behavior of Ferrocenecarboxaldehyde and some Ferrocene Schiff's Base Derivatives
- 1 January 1975
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals
- Vol. 30 (3-4) , 209-212
- https://doi.org/10.1080/15421407508083432
Abstract
The state of ferrocenecarboxaldehyde between 43.5° and 123.5° has been characterized as a non-birefringent, highly viscous phase having the following enthalpies and entropies of transition: 43.5°: 3.0 kcal/mole, 9.5 cal/deg.mole; 123.5°: 0.6 kcal/mole, 1.6 cal/deg.mole. Several p-substituted phenyl Schiff's bases of ferrocenecarboxaldehyde were synthesized and examined together with various other ferrocene derivatives. All exhibited normal crystal melting behavior.Keywords
This publication has 2 references indexed in Scilit:
- The effect of purity on the thermodynamic properties of cholesteryl heptadecanoateThermochimica Acta, 1970
- Some Acyl Ferrocenes and their ReactionsJournal of the American Chemical Society, 1957