Halogen exchange in platinum(IV) complexes
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 931-932
- https://doi.org/10.1039/c39730000931
Abstract
31 P N.m.r. spectra show that addition of an equimolar amount either of bromine to trans-[PtCl2(PR3)L](R = Et, L = py, 3,5-Me2-py, 4-But-py, PEt3; R = Bun, L = py)(py = pyridine) or of trans-[PtCl4(PEt3)(py)] to trans-[PtBr4(PEt3)(py)] results in halogen scrambling and gives an approximately statistical distribution of trans-[PtBrxCl4–x(PEt3)L](x= 0–4).Keywords
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