Synthesis and X-ray structural characterization of a novel oxyfluorinated microporous gallium phosphate with encapsulated 1,4-diazabicyclo[2.2.2]octane as the template: Ga3(PO4)(HPO4)2F3(OH)·C6N2H14·0.5 H2O
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 1197-1198
- https://doi.org/10.1039/c39920001197
Abstract
A gallophosphate with an open framework is synthesized; its structure consists of interconnecting Ga2O7ΦF2(Φ= O or OH) bioctahedra and PO4 tetrahedra, building up a thre-dimensional network around a novel (3126488) cage type, enclosing two 1,4-diazabicyclo[2.2.2]octane organic templates and leading to eight-membered channels along [001], six- and eight-rings along [101] and [010], the water molecule being located in the latter.Keywords
This publication has 8 references indexed in Scilit:
- A synthetic gallophosphate molecular sieve with a 20-tetrahedral-atom pore openingNature, 1991
- New Families of M(III)X(V)O4-Type Microporous Crystals and Inclusion CompoundsPublished by Elsevier ,1991
- Preparation and structural characterization of a novel galloarsenate using a dimethylamine templateJournal of the Chemical Society, Chemical Communications, 1989
- Preparation and structure of a gallium phosphate framework with clathrated isopropylamineActa Crystallographica Section C Crystal Structure Communications, 1986
- Preparation and structural characterization of two metallophosphate frameworks clathrating diprotonated ethylenediamine: AlPO4-12(en) and GaPO4-12(en)Inorganic Chemistry, 1985
- Some gallium phosphate frameworks related to the aluminium phosphate molecular sieves: X-ray structural characterization of {(PriNH3)[Ga4(PO4)4·OH]}·H2OJournal of the Chemical Society, Chemical Communications, 1985
- Aluminophosphate molecular sieves: a new class of microporous crystalline inorganic solidsJournal of the American Chemical Society, 1982
- Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenidesActa Crystallographica Section A, 1976