Reaction Kinetics of a Long Chain Molecule
- 1 December 1962
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 37 (11) , 2584-2586
- https://doi.org/10.1063/1.1733058
Abstract
A long chain molecule is considered, of which each segment carries a reactive group. It is assumed that the reactivity of each group depends upon whether zero, one, or two of its nearest neighbors have reacted. The average fraction of reacted groups is determined as a function of time. This is done by first deriving appropriate equations to describe the kinetics and then solving these equations. The results are illustrated by a number of graphs which show the average fraction of reacted groups as a function of time for different ratios of the reactivities.Keywords
This publication has 6 references indexed in Scilit:
- Reaction kinetics and tacticity of macromolecules. I. Methacrylic acid—ester copolymersJournal of Polymer Science, 1960
- Hydrolysis of polyacrylamide and acrylic acid–acrylamide copolymersJournal of Polymer Science, 1959
- Hydrolysis of methacrylic acid–methyl methacrylate copolymersJournal of Polymer Science, 1959
- A kinetic approach to the characterization of the “microtacticity” of a polymer chainJournal of Polymer Science, 1958
- Reaction Rates of Polyelectrolyte Derivatives. II. Effect of Neighboring Carboxyl on the Reactivity of p-Nitroanilide Groups1Journal of the American Chemical Society, 1958
- Reaction Rates of Polyelectrolyte Derivatives. I. The Solvolysis of Acrylic Acid–p-Nitrophenyl Methacrylate CopolymersThe Journal of Physical Chemistry, 1954