E.s.r. study of the cation radical of Rh2(O2CEt)4(PPh3)2; a ? electron radical
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 21,p. 945-946
- https://doi.org/10.1039/c39790000945
Abstract
Electrochemical or radiochemical oxidation of Rh2(O2CEt)4(PPh3)2 gives its cation radical, the e.s.r. spectra of which reveal that the odd electron orbital has σ symmetry with respect to the P–Rh–Rh–P axis and that the odd electron is distributed over the phosphorus and rhodium atoms.Keywords
This publication has 0 references indexed in Scilit: