Oxidative addition of hydrogen cyanide, hydrogen sulphide, and other acids to triphenylphosphine complexes of iridium(I) and rhodium(I)
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2516-2520
- https://doi.org/10.1039/j19680002516
Abstract
The interactions of hydrogen cyanide, hydrogen sulphide, toluene thiols, fluorocarboxylic, nitric, and perchloric acids with trans-chlorocarbonylbis(triphenylphosphine)iridium(I), and of some of these molecules with chlorotris(triphenylphosphine)rhodium(I) and other iridium and rhodium complexes, have been studied. The products of oxidative addition, which normally have a metal–hydrogen bond, have been studied by infrared and n.m.r. spectroscopy as well as by chemical techniques.Keywords
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