Facile synthesis of ferrocenyl silyl ethers and their utility as synthetic equivalents of hydroxyferrocenes
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 2123-2124
- https://doi.org/10.1039/cc9960002123
Abstract
The reactions of trialkylsilyltrifluoromethanesulfonic acid esters with four different cyclopent-2-en-1-ones afford the respective cyclopentadienyl silyl ethers, which can be transformed into the respective ferrocenyl silyl ethers in good yields; cleavage of the silyl ethers under basic conditions leads leads, via hydroxyferrocenes, to ferrocenyl–alkyl ethers.Keywords
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