Synthesis of α,β-Unsaturated Selenoamides by the Condensation Reaction of Lithium Eneselenolate Generated from Selenoacetamide with Aldehydes
- 1 July 1997
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1997 (7) , 775-776
- https://doi.org/10.1055/s-1997-5781
Abstract
The reaction of lithium eneselenolate generated from selenoacetamide and LDA with aldehydes gave α,β-unsaturated selenoamides in good to high yields. The successive addition of n-butyllithium and 3-bromo-1-propene to α,β-unsaturated selenoamide 3a gave selenoamide 7 with high selectivity.Keywords
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