Magnetic properties of R2Fe14B single crystals

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Abstract
A whole new class of high‐performance permanent magnet materials is based on the ternary tetragonal structure R2Fe14B, where R is one of the rare‐earth elements. We have successfully grown single crystals of this structure with R=Y, Nd, and Tb. Y is a nonmagnetic rare‐earth substitute, while Nd and Tb couple ferro‐ and ferrimagnetically, respectively, relative to the iron moment. All three of the compounds have [001] easy axes at room temperature, although the Nd compound exhibits a spin reorientation away from the [001] below about 150 K. Nd2Fe14B has a saturation induction at room temperature of 16.2 kG, which places an upper limit of approximately 65.6 MGOe on the energy product obtainable by magnets based on that material. While Tb2Fe14B exhibits a smaller magnetization because of ferrimagnetic coupling of the rare earths and the iron, it also has an extremely large magnetic anisotropy which is nearly temperature independent between 4.2 and 300 K.