Intramolecular homolytic displacement of bromine atoms from carbon in the reaction of but-3-enyl bromides with radicals
- 1 January 1980
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 498-499
- https://doi.org/10.1039/c39800000498
Abstract
The homolytic displacement of bromine atoms from 1-bromo-1-cyano-2,2-dimethylbut-3-ene by trichloromethyl radicals takes place by a stepwise mechanism in which a trichloromethyl radical attacks carbon-4 to give an intermediate radical which can undergo an intramolecular cyclisation with loss of a bromine atom or a radical transfer reaction with the addend.Keywords
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