Optical activity of trigonal coordination compounds
- 1 September 1962
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 5 (5) , 475-483
- https://doi.org/10.1080/00268976200100531
Abstract
The optical activity of trigonal coordination compounds is investigated using the crystal field theory. The ionic model is shown to account for the circular dichroism of Co(en)3 +3. The absolute configuration of Cr(C2O4)3 -3 is assigned on the basis of the ionic model.Keywords
This publication has 14 references indexed in Scilit:
- PARTIAL CHROMATOGRAPHIC RESOLUTION, ROTATORY DISPERSION, AND ABSOLUTE CONFIGURATION OF OCTAHEDRAL COMPLEXES CONTAINING THREE IDENTICAL BIDENTATE LIGANDSJournal of the American Chemical Society, 1961
- Strain-Induced Effects on the Degenerate Spectral Line of Chromium in MgO CrystalsPhysical Review B, 1961
- Optical Rotatory Dispersion of Transition-Metal ComplexesThe Journal of Chemical Physics, 1960
- Absorption Spectra of Cr3+ in Al2O3 Part B. Experimental Studies of the Zeeman Effect and Other Properties of the Line SpectraJournal of the Physics Society Japan, 1958
- Absorption Spectra of Cr3+ in Al2O3 Part A. Theoretical Studies of the Absorption Bands and LinesJournal of the Physics Society Japan, 1958
- Intensities in inorganic complexesJournal of Molecular Spectroscopy, 1958
- Studies on Crystals of Metallic Tris-ethylenediamine-complexes. II. The Crystal Structure of Sodium d-Tris-ethylenediamine-cobalt(III) Chloride Hexahydrate, 2d-[Co en3]Cl3·NaCl·6H2OBulletin of the Chemical Society of Japan, 1957
- Optical Rotatory Dispersion of Transition-Metal ComplexesThe Journal of Chemical Physics, 1956
- Studies on Crystals of Metallic Tris-ethylenediamine-complexes. I. The Crystal Structure of Dl-Tris-ethylenediamine-cobalt (III) Chloride Trihydrate, [Co en3]Cl3·3H2OBulletin of the Chemical Society of Japan, 1956
- The crystal structure of potassium trioxalatochromate (III), K3[Cr(C2O4)3]H2OActa Crystallographica, 1952