Rapid formation of a potent nitrosating agent by solvolysis of ionic nitrite in dichloromethane
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 955-956
- https://doi.org/10.1039/c39870000955
Abstract
Bis(triphenylphosphine)nitrogen(1+) nitrite reacted extensively with dichloromethane at 25 °C to produce an intermediate that converted secondary amines also present in these solutions into carcinogenic nitrosamines in high yields.Keywords
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