Spectrum and Magnetic Properties of Hexagonal DyCl3
- 1 November 1961
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 35 (5) , 1535-1548
- https://doi.org/10.1063/1.1732108
Abstract
The absorption and fluorescence spectra of anhydrous DyCl3 were investigated and the levels up to 37 000 cm—1 above the ground state established. Conclusive evidence is presented that the levels below 15 000 cm—1 belong to the 6H and 6F multiplets. The Zeeman effects show considerable nonlinear interactions which follow quantitatively the existing theory. The 12 low levels and their electric and magnetic field splittings are reasonably well represented by the simplified theory with L‐S coupling, with the approximate crystal parameters B20=A20〈r2〉 =89.8 cm—1, B40=—40.0 cm—1, B60=—23.3 cm—1, B66=253 cm—1.Keywords
This publication has 9 references indexed in Scilit:
- Infrared Absorption Spectrum of NdCl3The Journal of Chemical Physics, 1960
- Absorptionsspektrum und Zeeman-Effekt von kristallinen Dysprosiumsalzen bei tiefen TemperaturenThe European Physical Journal A, 1960
- The Matrix Elements of Tensor Operators for the Electronic ConfigurationsfnProceedings of the Physical Society, 1959
- Paramagnetic Resonance in Rare Earth TrichloridesThe Journal of Chemical Physics, 1958
- Energy levels in rare-earth ionsProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1957
- Absorption Spectra of Dysprosium(III), Holmium(III), and Erbium(III) Aquo Ions.Acta Chemica Scandinavica, 1957
- Absorption, Fluorescence, and Energy Levels of the Dysprosium Ion*Journal of the Optical Society of America, 1956
- Matrix Elements and Operator Equivalents Connected with the Magnetic Properties of Rare Earth IonsProceedings of the Physical Society. Section A, 1952
- Elektronenterme und Strahlung von Atomen in Kristallen. I. Termaufspaltung und elektrische DipolstrahlungAnnalen der Physik, 1948