Synthesis and Some Properties of Potassium Peroxofluorozirconate (IV) Species
- 1 January 1977
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 7 (5) , 413-419
- https://doi.org/10.1080/00945717708069718
Abstract
Two types of solid potassium peroxofluoro zirconate (IV) species have been synthesised for the first time. They are K3. Zr2. (O2)2. F7. (0.6–2) H2O and K2. Zr2. (O2)2. F6. (4–5) H2O. The first species is formed when the zirconium to fluoride mole ratios initially employed for the preparation are in the range 1:5 to 1:7, whereas the second one is formed when Zr (IV): F− employed for the preparation is 1:3.Keywords
This publication has 2 references indexed in Scilit:
- The potentiometric determination of fluorine in nuclear fuel reprocessing solutionsAnalytica Chimica Acta, 1969
- Studies on transition-metal peroxy-complexes. Part VI. Vibrational spectra and structureJ. Chem. Soc. A, 1968