Tobacco Chemistry. 37. The Absolute Configuration of Prenylsolanone, (9S)-6,12-Dimethyl-9-isopropyltrideca-5E,10E,12-trien-2-one, a Northunberganoid of Nicotiana tabacum L..
- 1 January 1976
- journal article
- research article
- Published by Danish Chemical Society in Acta Chemica Scandinavica
- Vol. 30b (2) , 178-179
- https://doi.org/10.3891/acta.chem.scand.30b-0178
Abstract
Ozonolytic degradation to (2S)-5-oxo-2-isopropylhexanal estabished the absolute configuration of prenylsolanone as S in agreement with chirality of other tobacco constituents assumed to be normal thunberganoids. 13C NMR results confirmed the E-configuration previously assigned to the 5,6-double bond.This publication has 1 reference indexed in Scilit:
- (6S)-6-Isopropyl-3-methyl-9-oxo-2E, 4E-decadienoic Acid from Turkish Nicotiana tabacum L., Assignment of Absolute ConfigurationAgricultural and Biological Chemistry, 1975