Medium effects in nuclear magnetic resonance. VII. Vapor phase studies of hydrogen bonding in methanol and methanol–trimethylamine mixtures
- 15 February 1969
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 47 (4) , 625-629
- https://doi.org/10.1139/v69-096
Abstract
The self association of methanol, and the intermolecular association of methanol and trimethylamine have been examined in the vapor phase using nuclear magnetic resonance spectroscopy. Values of ΔH and ΔS for the two systems have been found to be −4.1 ± 0.5 kcal/mole and −17.5 ± 3 e.u., and −5.8 ± 0.7 kcal/mole and −22.6 ± 3 e.u., respectively.Keywords
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