Inelastic neutron scattering measurements on [Cu4OCl6L4] (L = pyridine or dimethyl sulfoxide). Observation of zero-field splitting of the cluster ground state
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 2039-2044
- https://doi.org/10.1039/a700156h
Abstract
Inelastic neutron scattering measurements on the complexes [Cu 4 OCl 6 L 4 ] (L = pyridine or dimethyl sulfoxide) revealed ground-state zero-field splittings of ca. 3 and 6 cm -1 . The splittings are interpreted as due to the combined effects of exchange and spin–orbit coupling, and suggest a new interpretation of previous magnetic data.Keywords
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