Mesomorphic phenanthroline derivatives: novel architectures based on hydrogen bondingElectronic supplementary information (ESI) available: FT-IR spectra of compounds L12 and 1′16 and X-ray diffraction pattern of the palladium complex of L16. See http://www.rsc.org/suppdata/cc/b1/b110239g/

Abstract
Strong hydrogen bonding has been observed in mesomorphic phenanthroline compounds engineered from diacylaminobenzene platforms: a columnar organization is found in the free ligands (n = 12 or 16) whereas a smectic arrangement is evidenced in a palladium complex (n = 16).
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