Magnetic double resonance studies of some trans-bis(triethylphosphine) complexes of platinum
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 21,p. 2370-2373
- https://doi.org/10.1039/dt9730002370
Abstract
The 1H n.m.r. spectra of 44 platinum complexes containing trans-triethylphosphine ligands, with halide, hydride, and silyl or germyl ligands, have been recorded. Heteronuclear double resonance experiments have been used to determine 31P and 195Pt chemical shifts, as well as the signs of coupling constants, and the magnitudes of coupling constants not observed in the 1H spectra. Systematic trends in some of the parameters enable estimates of these parameters to be made for some complexes that have not been studied.Keywords
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