The Microstructure of Diene Polymers. I. Polyisoprenes and Polybutadienes Prepared at High Temperatures
- 1 December 1954
- journal article
- Published by Rubber Division, ACS in Rubber Chemistry and Technology
- Vol. 27 (4) , 954-958
- https://doi.org/10.5254/1.3543546
Abstract
In a previous paper a method has been described by which the microstructure of synthetic polyisoprenes can be deduced from intensity measurements in the infrared spectrum of these polymers. Similar analyses have been made in the case of polybutadienes by Hart and Meyer and by Hampton. It is the purpose of the present paper to present the results of structural determinations on polyisoprenes and polybutadienes prepared by bulk thermal polymerization in the temperature range 100 to 250° C.Keywords
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