Rate-enhancing multi-site interaction in the hydrolysis of a cationic ester catalysed by a Cu2+ complex of an anionic surfactant ligand in anionic sodium dodecyl sulfate micelles
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 691-692
- https://doi.org/10.1039/c39950000691
Abstract
The rate of hydrolysis of 2-nitro-4-trimethylammoniophenyl 2-picolinate is remarkably enhanced when catalysed by a Cu2+ complex of surfactant imidazole ligand possessing 2-hydroxymethyl and anionic charged groups in the co-micelles of sodium dodecyl sulfate; the rate enhancement is discussed in terms of multi-site interaction in the formation of a reactive ternary complex.Keywords
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