Diffusivity of the Hard-Sphere Model in the Region of Fluid Metastability
- 19 October 1981
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 47 (16) , 1129-1132
- https://doi.org/10.1103/physrevlett.47.1129
Abstract
New data are analyzed for the hard-sphere fluid at densities in the metastable range. In this region the diffusion coeffiecient behaves as in laboratory fluids, following a Doolittle equation with normal parameters rather than a Batchinski-Hildebrand equation. The diffusing, internally equilibrated, metastable fluid can be arrested at different densities by sudden "quenching" to obtain the glassy state. A new high-density limit for random close packing, 3% greater than that of Bernal packing, is identified.
Keywords
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