Evidence of repulsive interactions between NO, O, and N on Ir(110). A fast x-ray photoelectron spectroscopy study

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Abstract
The adsorption of NO on Ir(110) was studied in the temperature range from 200 to 500 K with fast x-ray photoelectron spectroscopy (XPS) using synchrotron radiation. Only three surface species were observed: molecular NO, atomic O, and atomic N. NO dissociation starts at temperatures higher than 300 K and molecular NO can coadsorb with Oads in the whole temperature region studied. By collecting O 1s and N 1s spectra within a few seconds we obtained information on the interaction between Nads, Oads, and NOads with increasing coadsorbate coverage. The Nads–Oads interaction has been found to be strongly repulsive. As a consequence, the Nads is destabilized already at moderate coverages and temperatures above 350 K leading to the removal of Nads from the surface in the form of N2 desorption.