The Electrochemistry of V[sub 2]O[sub 5] in LiCl-KCl Eutectic Melt
- 1 January 1962
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 109 (5) , 413-419
- https://doi.org/10.1149/1.2425434
Abstract
The electrochemistry of in an eutectic melt has been investigated with the aid of several electroanalytical techniques. Independent measurements with voltammetry, chronopotentiometry, and constant current electrolysis indicate that is reduced to a mixed lithium vanadium oxide (lithium vanadium bronze) on the electrode surface at a potential which is a function of concentration. Lithium vanadates of limited solubility are also formed during the reduction. Lithium vanadium bronzes which were obtained by the thermal decomposition of and do not agree in chemical and x‐ray analysis with those obtained by the electrochemical reduction of .Keywords
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