Living polymerization of substituted acetylenes by MoCl5- and MoOCl4-based catalysts
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1805-1806
- https://doi.org/10.1039/c39870001805
Abstract
New catalyst systems composed of MoCl5(or MoOCl4), Bun 4Sn, and-ethanol (molar ratio 1:1:0.5) effect living polymerisations of 1-chloro-oct-1-yne and o-(trimethylsilyl)phenylethyne, which are the first examples of living polymerisation of acetylenes.Keywords
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