Alpha-cleavage in amine molecular ions. A not-so-simple simple cleavage
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 996-997
- https://doi.org/10.1039/c39850000996
Abstract
Specific release of translational energy for methyl radical expulsion from certain t-butylamine ions demonstrates the existence of reverse energy barriers to α-cleavage in these amine molecular ions; literature heats of formation of immonium ions may in consequence have a systematic error.Keywords
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