A synthesis of cis-15,16-dimethyldihydropyrene
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 22,p. 1555-1557
- https://doi.org/10.1039/c29700001555
Abstract
The synthesis of cis-15,16-dimethyldihydropyrene (7), the first example of a cis-15,16-dihydropyrene derivative, has been accomplished starting from syn-2,11-dithia[3,3]metacyclophane (3)via a Stevens' rearrangement of the corresponding bis-sulphonium fluoroborate followed by a Hofmann elimination of the resulting bis-sulphide (5).Keywords
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