Aryloxide ligand dependent reactivity of tantalum dihydride compounds with alkenes

Abstract
The tantalum dihydride compounds [Ta(OAr)2(L)n(Cl)(H)2](n= 2, OAr = 2,6-diphenyl- and 2,6-diisopropylphenoxide; n= 1, OAr = 2,6-di-tert-butylphenoxide) react with styrene to produce different organometallic products depending upon the nature of the aryloxide ligand.

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