Theory of Solid
- 1 May 1961
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 122 (3) , 726-738
- https://doi.org/10.1103/physrev.122.726
Abstract
Using a phenomenological approach, it is shown first that solid in equilibrium with liquid II along the phase separation line, as well as at pressures somewhat above the melting pressure, should have anomalous thermal properties over a finite temperature range or, at least, at isolated temperatures. Such a behavior of the solid results from a correlation of thermodynamic character of its thermal properties with those of the anomalous liquid. The predicted anomalies of the solid will then be effectively verified in terms of rigorous thermodynamics and somewhat incomplete data available on liquid and solid along the melting line over a finite temperature interval. A specific anomaly of the melting pressure consisting in a shallow temperature minimum will be predicted at low temperatures, where both the liquid and solid phases are assumed to exhibit normal static thermal properties. The persistence of the anomalous equilibrium properties of liquid II on solidification will be discussed qualitatively as suggesting a similar origin of these anomalies in both phases, such a situation having been shown previously to exist with respect to the thermal anomalies of liquid and solid .
Keywords
This publication has 22 references indexed in Scilit:
- Heat conduction and fountain pressure in liquid He IIAnnals of Physics, 1960
- Some Thermal Properties of Liquid Helium ThreePhysical Review B, 1960
- On the theory of liquid and solid He3Annals of Physics, 1959
- Thermal Excitations in LiquidPhysical Review B, 1958
- Volume Anomaly of LiquidArising from Its Nuclear Spin SystemPhysical Review B, 1958
- New experiments on the specific heat of liquid 4He below 0.7°KPhysica, 1957
- On the theory of the liquid He-4 phase transformationAnnals of Physics, 1957
- The Liquid-Solid Transformation in Helium from 1.6° to 4°KPhysical Review B, 1952
- The specific heat of liouid helium between 0.25 and 1.9°KPhysica, 1952
- The Liquid-Solid Transformation in Helium near Absolute ZeroPhysical Review B, 1950