N,N-dimethoxyamine; a new methylating, aminating, and epiminating reagent
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 261-262
- https://doi.org/10.1039/c39900000261
Abstract
Electrophilically catalysed cleavage of the N–O bond of N,N-dimethoxyamine results in the formation of singlet N-methoxynitrenium ion, which aminates soft nucleophiles, methylates hard ones, and epiminates alkenes.Keywords
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