Photolysis of diazocarbonyl compounds in allylic alcohols: new preparation of bicyclic lactones
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 822-823
- https://doi.org/10.1039/c39720000822
Abstract
Photolysis of dimethyl diazomalonate and ethyl diazoacetate in allylic alcohols gives the O–H insertion products of the carbene together with bicyclolactones; sensitized photolysis gives only bicyclolactones.Keywords
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