The novel selenium mediated aromatization of a 1,6-diyn-3-ene system related to neocarzinostatin chromophore
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 694-695
- https://doi.org/10.1039/c39910000694
Abstract
Treatment of 1,6-diyn-3-ene system 1 with SeO2 caused a Myers type cyclization to produce a biradical 6 through an enyne–allene system 5 which was generated by an ene reaction of 1 with SeO2, in analogy with the case of neocarzinostatin chromophore.Keywords
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