Variable temperature electrochemistry as a powerful method for conformational investigations on the fluxional organometallic complex Mo(His-Nɛ-C2H4CO2Me)(η-allyl)(CO)2 (His = Nδ, N,O-l-histidinate)
- 1 January 2001
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 1,p. 131-132
- https://doi.org/10.1039/b007822k
Abstract
Square-wave voltammograms of the complex Mo(His-Nε-C2H4CO 2Me)(η-allyl)(CO)2 (His = Nδ,N,O-L-histidinate) 2 recorded at variable temperatures establish the existence of two isomers in solution in both the reduced and the oxidized paramagnetic form of 2; a complete analysis yields thermodynamic parameters such as equilibrium constants, ΔG and ΔH for all species.Keywords
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