Synthesis and molecular structure of the unsymmetrically substituted magnesium alkyl Mg(Bun){CH[SPh][SiPh2(CH2NC5H10)]}
- 5 May 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 865-866
- https://doi.org/10.1039/b000494o
Abstract
The unsymmetrically substituted magnesium alkyl Mg(Bun){CH[SPh][SiPh2(CH 2NC5H10)]} (NC5H10 = 1-piperidyl) with a stereogenic metalated carbon atom is obtained by deprotonation of an (aminomethyl)[(phenylthio)methyl]silane with MgBunBus and examined by single crystal X-ray diffraction analysis and theoretical methods.Keywords
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