Parametrization of kinetic energy dependences of ion–polar molecule collision rate constants by trajectory calculations
- 15 March 1994
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 100 (6) , 4703
- https://doi.org/10.1063/1.466255
Abstract
Kinetic energy dependences of ion–polar molecule capture rate constants have been calculated using the trajectory method at varies temperatures. An empirical equation was formulated to fit the calculated data. The parametrized equation gives rate constants within 5% error for re- lative kinetic energies ranging from thermal to several eV and temperatures ranging from 50 K to 1000 K.Keywords
This publication has 8 references indexed in Scilit:
- Reactions of protonated water clusters with deuterated ammonia: H(H2O)+n (n = 1–4) + ND3International Journal of Mass Spectrometry and Ion Processes, 1992
- Erratum: Rotational temperature dependences of gas phase ion–molecule reactions [J. Chem. Phys. 8 9, 4848 (1988)]The Journal of Chemical Physics, 1989
- Rotational temperature dependences of gas phase ion–molecule reactionsThe Journal of Chemical Physics, 1988
- The Selected Ion Flow Tube (Sift): Studies of Ion-Neutral ReactionsPublished by Elsevier ,1988
- Kinetic energy dependence of ion-polar molecule collision rate constants by trajectory calculationsThe Journal of Chemical Physics, 1985
- Parametrization of the ion–polar molecule collision rate constant by trajectory calculationsThe Journal of Chemical Physics, 1982
- Collisions in a noncentral field: A variational and trajectory investigation of ion–dipole captureThe Journal of Chemical Physics, 1980
- Reactions of Gaseous Molecule Ions with Gaseous Molecules. V. TheoryThe Journal of Chemical Physics, 1958