Reactions of titana- and zircona-cyclopentadienes with alkynes
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 435-436
- https://doi.org/10.1039/c39830000435
Abstract
Expanded metallacycles of up to 17 members have been obtained from insertion reactions of acetylenic molecules into the M–C bonds of various substituted dicyclopentadienyl-titana- and -zircona-cyclopentadienes; in one case, a zirconacyclononatetraene with mixed phenyl and methyl substituents was isolated.Keywords
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