Über Derivate des Hydrazins, VII Darstellung und Charakterisierung von Bis(trimethylsilyl)aminoisocyanid.
Open Access
- 1 October 1976
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 31 (10) , 1317-1321
- https://doi.org/10.1515/znb-1976-1004
Abstract
By reaction of carbon tetrachloride with lithium tris(trimethylsilyl)hydrazide and then with lithium butyl a compound with formula (Me3Si)2N2C is formed. From the way of preparation, spectroscopic investigations, and chemical reactions the substance is characterized as bis(trimethylsilyl)aminoisocyanide (3). 3 hydrolyzes, and does not react with oxygen. The compound combines with chlorine and bromine forming aminoisocyanide dihalides, and with carbon disulfide forming an adduct. At higher temperatures 3 isomerizes to bis(trimethylsilyl)carbodiimide (1).Keywords
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