Antagonistic metal-directed inductions in catalytic asymmetric aziridination by manganese and iron tetramethylchiroporphyrins
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 989-990
- https://doi.org/10.1039/a901559k
Abstract
Catalytic asymmetric aziridination of styrene by [N-(p-toluenesulfonyl)imino]phenyliodinane was achieved by manganese and iron tetramethylchiroporphyrins; opposite enantioselectivities were obtained with the two metal centers, and possible mechanisms are proposed to explain this unexpected result.Keywords
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