Halogenation of bis[dicarbonyl(ethyltetramethylcyclopentadienyl)ruthenium(I)]; X-ray structure of tribromocarbonyl(ethyltetramethylcyclopentadienyl)ruthenium(IV)
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 547-548
- https://doi.org/10.1039/c39790000547
Abstract
Halogens react with the compound [Ru(η5-C5Me4Et)(CO)2]2 to give first the halogeno-bridged cation [{Ru(η5-C5Me4Et)(CO)2}2X]+ and then [Ru(η5-C5Me4Et)(CO)2X](X = Cl, Br, or I), the bromide reacts further with bromine to give [Ru(η5-C5Me4Et)(CO)Br3] whose X-ray structure is reported.Keywords
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